Kinetically stabilized dibenzoborole as an electron-accepting building unit.

نویسندگان

  • Atsushi Wakamiya
  • Kotaro Mishima
  • Kanako Ekawa
  • Shigehiro Yamaguchi
چکیده

A synthetic route to a dibenzoborole, kinetically stabilized by the 2,4,6-tri-tert-butylphenyl group, was developed, and a series of pi-extended derivatives were synthesized, which show orange-red emissions and stable electrochemical redox properties.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Bi-diketopyrrolopyrrole (Bi-DPP) as a novel electron accepting compound in low band gap π-conjugated donor–acceptor copolymers/oligomers

The synthesis and characterization of a novel 2,5-diketopyrrolo[3,4-c]pyrrole(DPP)-based accepting building block with the scheme DPP-neutral small linker-DPP (Bi-DPP) is presented, which was utilized as electron accepting moiety for low band gap π-conjugated donor-acceptor copolymers as well as for a donor-acceptor small molecule. The electron accepting moiety Bi-DPP was prepared via a novel s...

متن کامل

Global energy confinement scaling predictions for the kinetically stabilized tandem mirror

Transport is studied for the kinetically stabilized tandem mirror, an attractive magnetic confinement device for achieving a steady-state burning plasma. For a magnetohydrodynamic stable system, three different radial transport models with Bohm, gyro-Bohm, and electron temperature gradient ETG scaling are derived. As a conservative estimate, numerical coefficients in the models are taken to be ...

متن کامل

Organic rectifying junctions from an electron-accepting molecular wire and an electron-donating phthalocyanine.

Self-assembled monolayers (SAMs) of arylene-ethynylene oligomers that incorporate electron-accepting 9-fluorenone and 9-[(4-pyridyl)methylene]fluorene units in the backbone exhibit symmetrical current-voltage (I-V) characteristics, but rectifying junctions with current ratios of 20-80 at +/-1 V have been obtained by protonating these wire-like molecules and ionically coupling with anionic donors.

متن کامل

Novel quinoxaline-based organic sensitizers for dye-sensitized solar cells.

Novel quinoxaline-based organic sensitizers using vertical (RC-21) and horizontal (RC-22) conjugation between an electron-donating triphenylamine unit and electron-accepting quinoxaline unit have been synthesized and used for dye-sensitized solar cells (DSSCs), leading to the relatively high power conversion efficiencies of 3.30 and 5.56% for RC-21 and RC-22, respectively. This result indicates...

متن کامل

Decorating graphene nanosheets with electron accepting pyridyl-phthalocyanines.

We describe herein the preparation of novel exfoliated graphene-phthalocyanine nanohybrids, and the investigation of their photophysical properties. Pyridyl-phthalocyanines (Pcs) are presented as novel electron accepting building blocks of variable strengths with great potential for the exfoliation of graphite via their immobilization onto the basal plane of graphene in dimethylformamide (DMF) ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 5  شماره 

صفحات  -

تاریخ انتشار 2008